Publications
Oxygen Activation by Co(II) and a Redox Non-Innocent Ligand: Spectroscopic Characterization of a Radical–Co(II)–Superoxide Complex with Divergent Catalytic Reactivity. Journal of the American Chemical SocietyJournal of the American Chemical Society.
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2016. Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity. Journal of the American Chemical SocietyJournal of the American Chemical Society. 138(7):2327-2341.
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2016. A Synthetic Oxygen Atom Transfer Photocycle from a Diruthenium Oxyanion Complex. Journal of the American Chemical Society.
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2016. Two-Center/Three-Electron Sigma Half-Bonds in Main Group and Transition Metal Chemistry. Accounts of Chemical ResearchAccounts of Chemical Research.
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2016. Axial Ligand Coordination to the C–H Amination Catalyst Rh2(esp)2: A Structural and Spectroscopic Study. Inorganic Chemistry. 54(17):8817-8824.
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2015. Completing the series of Group VI heterotrimetallic M2Cr(dpa)4Cl2 (M2 = Cr2, Mo2, MoW and W2) compounds and investigating their metal–metal interactions using density functional theory. Inorganica Chimica Acta. 424:241-247.
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2015. Electrolyte Dependence of CO2 Electroreduction: Tetraalkylammonium Ions Are Not Electrocatalysts. ACS CatalysisACS Catalysis. 5(2):703-707.
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2015. Electronic Structure of Ni2E2 Complexes (E = S, Se, Te) and a Global Analysis of M2E2 Compounds: A Case for Quantized E2n– Oxidation Levels with n = 2, 3, or 4. Journal of the American Chemical SocietyJournal of the American Chemical Society. 137(15):4993-5011.
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2015. Electronic Structure of Ru2(II,II) Oxypyridinates: Synthetic, Structural, and Theoretical Insights into Axial Ligand Binding. Inorganic Chemistry. 54(17):8571-8589.
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2015. Heterometallic Second-Row Transition Metal Chain Compounds in Two Charge States: Syntheses, Properties, and Electronic Structures of [Mo–Mo–Ru]6+/7+ Chains. Inorganic Chemistry. 54(15):7660-7665.
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2015. Metal–metal multiple bonded intermediates in catalysis. Journal of Chemical Sciences. 127(2):209-214.
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2015. Not all density functionals are created equal: the case of the missing electron in the oxidized [W-W-O]7+ core. Chemical Communications. 51(44):9153-9156.
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2015. Electronic tuning of Mo2(thioamidate)4 complexes through [small pi]-system substituents and cis/trans isomerism. Dalton Transactions. 43(16):6165-6176.
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2014. Heterometallic Multiple Bonding: Delocalized Three-Center σ and π Bonding in Chains of 4d and 5d Transition Metals. Inorganic Chemistry. 53(21):11354-11356.
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2014. An “Intermediate Spin” Nickel Hydride Complex Stemming from Delocalized Ni2(μ-H)2 Bonding. Journal of the American Chemical SocietyJournal of the American Chemical Society. 136(39):13538-13541.
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2014. Oxidative Stretching of Metal–Metal Bonds to Their Limits. Inorganic Chemistry. 53(9):4777-4790.
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2014. Progress in Inorganic Chemistry: Metal-Metal Bond-Containing Complexes as Catalysts for C-H Functionalization. Progress in Inorganic Chemistry. 58:225.
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2014. Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex. Science.
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2013. Lewis Acid Enhanced Axial Ligation of [Mo2]4+ Complexes. Inorganic Chemistry.
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2013. A Synthetic Cycle for Nitrogen Atom Transfer Featuring a Diruthenium Nitride Intermediate. European Journal of Inorganic Chemistry.
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2013. Assessing Metal–Metal Multiple Bonds in Cr-Cr, Mo-Mo, and W-W Compounds and a Hypothetical U-U Compound: A Quantum Chemical Study Comparing DFT and Multireference Methods. Chemistry – A European JournalChemistry – A European Journal. 18:1737-1749.
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2012. A convenient, high-yielding, chromatography-free method for the insertion of transition metal acetates into porphyrins. Polyhedron. :-.
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2012. Covalent Attachment of Catalyst Molecules to Conductive Diamond: CO2 Reduction Using “Smart” Electrodes. Journal of the American Chemical SocietyJournal of the American Chemical Society.
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2012. Dirhodium Catalysts That Bear Redox Noninnocent Chelating Dicarboxylate Ligands and Their Performance in Intra- and Intermolecular C–H Amination. European Journal of Inorganic ChemistryEuropean Journal of Inorganic Chemistry. 2012:562-568.
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2012. Electrophilic Aryl C-H Amination by Dimetal Nitrides: Correlating Electronic Structure with Reactivity. Chemical Science. :-.
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2012. Introducing a Mixed-Valent Dirhodium(II,III) Catalyst with Increased Stability in C-H Amination. Chemical Communications. :-.
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2012. Jahn-Teller distortion, ferromagnetic coupling, and electron delocalization in a high-spin Fe–Fe bonded dimer. Polyoxometalates, metal wires and other “polymetallic” complexes: structure, properties, theoretical modelling A tribute to Marie-Madeleine Rohmer. 15(2–3):192-201.
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2012. The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates. Dalton Transactions. 41(3):700-713.
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2012. Synthesis, characterization and thermal properties of trimetallic N3-Cr-CrM-N3 azide complexes with M = Cr, Mn, Fe, and Co. Dalton Transactions. 41(26):8153-8161.
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2012. X-Ray Absorption Spectroscopic, Crystallographic, Theoretical (DFT) and Chemical Evidence for a Chalcogen–Chalcogen Two Center/Three Electron Half Bond In an Unprecedented “Subselenide” Se23− Ligand. Chemistry – A European JournalChemistry – A European Journal. :n/a-n/a.
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2012. Aryl C–H Amination by Diruthenium Nitrides in the Solid State and in Solution at Room Temperature: Experimental and Computational Study of the Reaction Mechanism. Journal of the American Chemical SocietyJournal of the American Chemical Society. 133(33):13138-13150.
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2011. Chemically Reversible Four-Electron Oxidation and Reduction Utilizing Two Inorganic Functional Groups. Journal of the American Chemical SocietyJournal of the American Chemical Society. 133(9):2856-2859.
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2011. Evidence for a One-Electron Mechanistic Regime in Dirhodium-Catalyzed Intermolecular C-H Amination. Chemistry – A European JournalChemistry – A European Journal. 17:5827-5832.
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2011. Group 6 Complexes with Iron and Zinc Heterometals: Understanding the Structural, Spectroscopic, and Electrochemical Properties of a Complete Series of M M···M′ Compounds. Inorganic ChemistryInorganic Chemistry. 50(16):7650-7661.
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2011. Remote Effects of Axial Ligand Substitution in Heterometallic Cr≡Cr···M Chains. Inorganic ChemistryInorganic Chemistry. 50(21):10592-10599.
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2011. Aryl C−H Bond Amination by an Electrophilic Diruthenium Nitride. Journal of the American Chemical SocietyJournal of the American Chemical Society. 132(35):12228-12230.
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2010. Crystals in Which Some Metal Atoms are More Equal Than Others: Inequalities From Crystal Packing and Their Spectroscopic/Magnetic Consequences. Journal of the American Chemical SocietyJournal of the American Chemical Society. 132(40):14261-14272.
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2010. A Definitive Answer to a Bonding Quandary? The Role of One-Electron Resonance Structures in the Bonding of a {Cu3S2}3+ Core Chemistry – A European JournalChemistry – A European Journal. 16:2719-2724.
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2010. Chloro and Azido Diruthenium Complexes Bearing Electron-Rich N,N′,N′′-Triphenylguanidinate Ligands. Inorganic ChemistryInorganic Chemistry. 48(20):9846-9852.
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2009. Oxidation Chemistry of Axially Protected Mo2 and W2 Quadruply Bonded Compounds. Inorganic ChemistryInorganic Chemistry. 48(24):11889-11895.
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2009. Remarkable regioselectivity in the preparation of the first heterotrimetallic MoWCr chain. Chemical Communications. (29):4357-4359.
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2009. Terminal nitrido and imido complexes of the late transition metals.. Comments on Inorganic Chemistry: A Journal of Critical Discussion of the Current Literature. 30(1-2)
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2009. Delocalized Metal–Metal and Metal–Ligand Multiple Bonding in a Linear RuRuN Unit: Elongation of a Traditionally Short RuN Bond. Angewandte Chemie International EditionAngewandte Chemie International Edition. 47:10102-10105.
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2008. Diamagnetic Corrections and Pascal's Constants. Journal of Chemical EducationJournal of Chemical Education. 85(4):532.
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2008. Do Metal–Metal Multiply-Bonded “Ligands” Have a trans Influence? Structural and Magnetic Comparisons of Heterometallic CrCr···Co and MoMo···Co Interactions European Journal of Inorganic ChemistryEuropean Journal of Inorganic Chemistry. 2008:5569-5572.
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2008. Electronic structure and spectroscopy of "superoxidized" iron centers in model systems: theoretical and experimental trends. Physical Chemistry Chemical Physics. 10(30):4361-4374.
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2008. Introducing a Metal−Metal Multiply Bonded Group as an “Axial Ligand” to Iron: Synthetic Design of a Linear Cr−Cr···Fe Framework. Journal of the American Chemical SocietyJournal of the American Chemical Society. 129(42):12684-12685.
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